A direct synthesis of hydroxysemperoside deglucoside

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A direct synthesis of hydroxysemperoside deglucoside

A 1 0-step synthesis of hydroxysemperoside deglucoside has been achieved. The key step is an organopalladium-mediated cyclization that produces a highly functionalized oxabicyclooctane. The remaining functional groups are introduced by addition to the exo face of the fused bicyclic system.

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ژورنال

عنوان ژورنال: Journal of the American Chemical Society

سال: 1989

ISSN: 0002-7863,1520-5126

DOI: 10.1021/ja00208a012